Investigation of water treatment sludge from drinking water treated with Zetafloc 553I coagulant for phosphorus removal from wastewater

Abstract

Water treatment sludge have shown promising results as adsorbent for phosphorus and sulphate removal from real wastewater. The study was conducted through batch kinetics and equilibrium isotherm modes. The chemical composition reveal that aluminium compounds were dominant in the fresh sludge and aluminium phosphates were also observed in the used sludge. The results reveal that Manganese was leached from the material at all pH values investigated with the highest level observed at pH 2 and all concentrations higher than the national standard of discharge into the relevant environment. The point of zero charge of the adsorbent was pH 8.04 and high adsorption capacities for both sulphate and phosphate ions were observed at pH values lower than this point. Batch kinetic results revealed 96.0 ± 3.0% sulphates removal in the first 30 min whereas the highest phosphates removal was 88.0 ± 4.0% attained at 300 min of the experiment. Pseudo - second order reaction fitted the data better than Pseudo-first order reaction. The percentage removal of sulphates was observed decreasing with increasing adsorbent dose after 2.4 g dose but removal increased with increasing media dosage for phosphorus. The equilibrium data was better described by Freundlich isotherm with constants relating to adsorption capacities being 6.76 and 6.2 L g−1 respectively, for sulphates and phosphates adsorption. The adsorption capacity of phosphates was observed decreasing with increasing temperature, but the results were not conclusive in the case of sulphates. The results reveal that copper, nickel, and zinc have affinity for sulphates. The water treatment sludge can be used for phosphate and sulphate removal from wastewater though the leachability of manganese is a concern. Further investigations through fixed bed columns will need to be investigated before field trials. In conclusion, the sludge can be used as adsorbent for phosphorus and sulphates removal from wastewater through filtration and onsite treatment methods such as vertical or horizontal flow wetland systems. The success of the adsorbent will reduce the costs associated with its disposal which can also lead to leachability of metals into the environment with time.