Abstract

Spectroscopy in the wavelength region of 330 nm to 400 nm for highly charged tungsten was performed using the High Temperature Super Conducting Electron Beam Ion Trap (SH-HtscEBIT) at Fudan University. Three lines from palladium-like tungsten (W28+) were identified as transitions between metastable levels in the first excited configuration ([Kr]4d94f). A second-order relativistic many-body perturbation theory approach and a simple collisional radiative model were used to theoretically study the fine structure levels of the 4d94f configuration. The calculated results show qualitative agreement with experiment. We conclude that some levels in the 4d94f excited configuration have extremely long lifetimes and may exhibit extraordinarily high populations, possibly leading to indirect ionization in, for example, fusion plasmas.

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