Abstract
The extent of the crystalline solutions in the system CaO‐MgO‐V2Os was studied quantitatively by the determination of lattice parameters. Metavanadate solutions existed along the length of the CV‐MV join, while the defect garnet solutions occurred at 29 to 32 mol% MgO on the orthovanadate join. The addition of solute ions created structural changes in the directions of the polyhedral layers (a‐ and c‐axis directions). Little change was reflected in the direction of polyhedral chains (b‐axis direction). The amount of solute allowed into the host lattices was structurally limited due to the significant differences in size between Mg2+ and Ca2+.
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