Abstract
The room-temperature solid-state reactions occurring in the preparation of nanotubes ofzinc sulfide are further investigated by x-ray powder diffractometry (XRD) and infra-red(IR) spectrometry measurements, and the nanotube ZnS product obtained is measured byZ-scan technology to investigate the third-order nonlinear optical (NLO) properties. TheXRD result suggests that the reactions leading to the formation of the nanotubules haveoccurred through reaction-controlled to growth-controlled procedures, and the IR resultindicates that the procedures involve a coordination effect of the additive DABCO asligand on the reactant. The result of NLO measurements shows that the nanotubeZnS products obtained have the behaviours of the third-order nonlinear opticalproperties of both NLO absorption and NLO refraction with self-focusing effects.
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