Abstract

In the present study, the sustained-release system loading citral was synthesised by using PNIPAm nanohydrogel as a carrier and analysed its drug-release kinetics and mechanism. Four release models, namely zero-order, first-order, Higuchi, and Peppas, were employed to fit the experimental data, and the underlying action mechanism was analysed. The optimised system was applied to treat a bamboo mould, followed by assessment of the mould-proof performance. Our experimental results revealed that the release kinetics equation of the system conformed to the first order; the higher the external temperature, the better the match was. In the release process, PNIPAm demonstrated a good protection and sustained-release effect on citral. Under the pressure of 0.5 MPa, immersion time of 120 min, and the system concentration ratio of 1, the optimal drug-loading parameters were obtained using the slow-release system with the best release parameters. Compared to the other conditions, bamboos treated with pressure impregnation demonstrated a better control effect on bamboo mould, while the control effect on Penicillium citrinum, Trichoderma viride, Aspergillus niger, and mixed mould was 100% after 28 days. Moreover, the structure and colour of bamboo remained unchanged during the entire process of mould control.

Highlights

  • Parallel to the excessive carbon dioxide emissions, the emission of greenhouse gases has increased considerably, making climate change a global challenge for mankind

  • The maximum absorption peak of citral was obtained at 238 nm (Figure 2A), while PNIPAm/citral nanohydrogel (P/Cn) showed a large absorption value at the same wavelength, which was similar to the maximum absorption wavelength of 240 nm and was not interfered with other substances

  • The standard solution of citral-PBS with a concentration of 2–8 μg/mL was prepared, and the absorbance value was measured at the wavelength of 238 nm

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Summary

Introduction

Parallel to the excessive carbon dioxide emissions, the emission of greenhouse gases has increased considerably, making climate change a global challenge for mankind. Following the ‘carbon neutral’ goal of the Paris Agreement, the global market demand for low-carbon materials has been increasing [1,2]. As a natural low-carbon material, bamboo offers the advantages of sustainable logging and utilisation, high strength to weight ratio, high strength, and biodegradability [3,4,5]. It is commonly used in the construction, furniture, and interior decoration industries and has significant application prospects in the aerospace domain [6,7,8,9]. Research on bamboo mould prevention can effectively improve the utilisation efficiency of bamboo and play a positive role in realising the vision of a carbon-free future

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