Abstract
The Mn 2+-F − distance for Mn 2+-doped CaF 2, CdF 2, SrF 2 and BaF 2 is derived from the experimental isotropic superhyperfine constant A s. The results obtained indicate the existence of inwards relaxation processes in all these cases, as well as values of the Mn 2+-F − distance which are ≈0.1 A larger than those found for systems with [MnF 6] 4− units. This allows one to explain the low 10 D q values recently found by Alonso an Alcalá in CdF 2: Mn 2+.
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