Abstract

Abstract The vibrational ground state microwave spectrum of cis-cyclopropyl carbonyl chloride-(35Cl) was investigated in the region from 4 to 40 GHz by microwave Fourier transform (MWFT) spectroscopy. The rotational and fourth order centrifugal distortion constants were determined. The quadrupole hyperfine structure was assigned and the quadrupole coupling constants including the off-diagonal element i ab were evaluated. This leads to a transformation of the quadrupole coupling tensor into its principal axes system.

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