Investigation of the insulating properties of the Cherkasy deposit clays for the creation of underlying screens of radioactive waste at the ‘Vector’ site

Abstract

The lack of scientifically substantiated requirements, comprehensively developed and approved in a prescribed manner, for the usage of clays as a barrier material poses risks for the safe disposal of radioactive waste in facilities at the ‘Vector’ site for the period of their operation and closure. The bentonite clay from Ukraine’s largest Cherkasy deposit of bentonite and palygorskite clays is considered the most durable as the main component of the insulating (underlying) screens of radioactive waste disposal facilities. The main properties and compositional features of the Cherkasy natural bentonite clay (Dashukovskaya site, layer II) and its variety such as alkaline earth bentonite (activated soda bentonite), which provide isolation of radioactive waste in disposal, are considered. It is shown that the Cherkasy field has good waterproofing and barrier properties, including a high sorption capacity with respect to 90Sr and 137Cs, which is one of the main characteristics that ensure the safe disposal of radioactive waste. The alkaline earth bentonite absorbs 90Sr and 137Cs more efficiently than natural bentonite does. However, 90Sr is sorbed in larger quantities than 137Cs on both types of bentonite. With increasing time of interaction with an aqueous solution, both types demonstrate a redistribution of the mobile (exchangeable) and immobile (non-replaceable) forms of radionuclides. The contribution of the stationary form that does not participate in migration processes also increases. A comprehensive analysis of the bentonite clays of the Cherkasy deposit was carried out, taking into account the significance of recoverable reserves and the potential for improving the technical and economic parameters of clays. Thus, the Cherkasy bentonite clays can be recommended as an additional anti-migration engineering barrier for ground/near-surface facilities for the disposal of radioactive waste. When choosing the type of bentonite clay for use as a barrier in a radioactive waste disposal facility, one could take into account the data published in the article, but the question of applying the bentonite clays of the Cherkasy deposit to ensure the safe disposal of radioactive waste remains to be further studied.