Abstract
In the present work, the inhibiting effect of environmentally friendly cerium and phosphorus-based conversion films on zinc corrosion in 5% NaCl and 1 N Na2SO4 test media was investigated. The films were prepared by immersion and stirring in the passivating/converting solution for time periods of 3,5,7, 10 min., respectively. The chemical composition of the films was determined by EDX analysis. The results of the electrochemical studies showed that in 5% NaCl medium, cerium- and phosphorus-based films exhibited high inhibition effect only during the first days of polarization resistance (Rp) measurement. In 1 N Na2SO4 medium, the Rp of the conversion films was up to 2.5 times higher than that of pure zinc coatings throughout the test period.
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