Investigation of the impact of nitrogen and water vapor dilution in oxidizer stream on flame structure, soot production and extinction of a laminar ethylene-fueled co-flow diffusion flame

Abstract

This paper discusses the effect of nitrogen (N2) and water vapor (H2O) dilution in oxidizer stream on the flame structure, and soot production and extinction of laminar ethylene (C2H4)-fueled co-flow diffusion flame (CFDF). The total oxidizer stream flow rate is kept constant while varying the flow rates of air, N2, and H2O to achieve the desired oxygen concentration called oxygen index (OI). As OI reduces, the flame starts to lift off from the burner surface and shows upward and downward oscillations before extinction through blow-off. The OI at which the flame blows off is called the limited oxygen index (LOI), and it depends on burner configuration, fuel, and oxidizer flow conditions. LOI value for C2H4-fueled laminar CFDF were found to be 12.4% and 14% when the diluent was N2 and H2O, respectively. The experiment and simulation results are presented from 21% O2 concentration in oxidizer to very low oxygen concentration in oxidizer close to extinction. Through quantitative measurements of soot volume fraction (SVF), the result shows a notable reduction in the peak concentrations of SVF as the OI decreases. This decrease is more pronounced with H2O than N2 dilution. One-dimensional (1D) opposed flow diffusion flame simulations are performed to understand various effects of the addition of diluents like H2O and N2. It is observed that in addition to inert, thermal and diffusion effect of H2O in reduction of flame temperature and temperature-dependent production rate of key species, H2O also affects flame chemistry through OH + H2 = H + H2O, 2OH = O + H2O. As a result there is a further drop in the concentration of active radicals (like H, O) which leads to quicker soot inhibition and flame extinction.