Abstract
AbstractThe reactions of model molecules were considered to study the kinetics and the mechanism of the esterification and the alcoholysis reactions catalyzed by various metal compounds (Li, Na, K, Zn, Co, Mn, Ti). Ti was found to be the most active catalyst for both reactions and to be acting via a different mechanism (concerted). The possible structure of the active titanium intermediate was investigated by means of 1H‐ and 13C‐NMR spectroscopy, FT–IR spectroscopy, and electroconductivity.
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More From: Journal of Polymer Science Part A: Polymer Chemistry
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