Abstract
Abstract The electronic structure of SbCl 5 L complexes has been analyzed on the basis of the fluorescence spectra of the sulfur and chlorine atoms as well as quantum chemical XαDV and PM3 calculations. The results have been compared with the corresponding data for SnCl 4 L 2 and TiCl 4 L 2 complexes. An increase in electron density on the chlorine atoms accompanied by a decrease on the central metal atom has been observed for the complexes arranged according to their stability. The arrangement of Sn, Sb, and Ti complexes with dimethyl sulfide according to their increasing stability is in disagreement with the order of the complexes with respect to electron density on the sulfur atom.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
