Abstract

The paper presents the results of studies obtained with the development of the technology of electron-beam crucible impregnation of metallurgical silicon. It is shown that refining of silicon from background and dopant impurities in electron-beam crucible-free zone melting occurs by zone purification during melting and as a result of evaporation of impurities from the sample surface. The mathematical model and computational experiment were been performed to determine the temperature gradient at different rates of zone melting. It was found the diapason of temperature gradients, which provides the columnar structure of crystallites and the purification of the samplesdue the melting with the zone recrystallization procedure. The level of the resistivity of the ingots increases at the end.

Highlights

  • Photoelectric converters (FEC) of solar cells are made of silicon, and experts believe that in the near future there will be no competitive technology based on the use of other materials [1]

  • As one of the trends in the development of silicon production technology for solar energy, direct silicon production has been determined by directional crystallization methods from refined commercial silicon [1]

  • This is due to the different values of the temperature gradient arising at the boundary between the liquid and solid phases [7]

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Summary

Introduction

Photoelectric converters (FEC) of solar cells are made of silicon, and experts believe that in the near future there will be no competitive technology based on the use of other materials [1]. The method of crucible-free electron-beam zone recrystallization used in this paper makes it possible to purify silicon determined by these three basic principles.The second and third statements are based on carrying out the process in a high vacuum and the difference in the vapor pressure of the various elements, which will lead to the removal of components for which. Specific electrical resistance is one of the most important parameters determining the quality of semiconductor silicon This parameter characterizes the degree of purity of semiconductor materials [3].The cyclograms of the process of electron-beam crucible-free zone melting of metallurgical silicon were developed. Melting of the samples was carried out at velocities of 0.0056 mm/s; 0.014 mm/s; 0.028 mm/s; 0.039 mm/s; 0.056 mm/s.In Fig. 2 shows the cyclograms of the electron-beam crucible zone melting process of silicon polycrystals for melting rates of 0.0056 - 0.056 mm/s.

Cd In Sn Ag Ba W Ag Au Bi
Calculations showed that at crystallization rates of
Findings
Conclusions
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