Abstract
Molecular beam mass spectrometry with photoionizationby synchrotron radiation was used to study the structure of flat premixed flames of C2H4/O2/Ar and C2H4/C2H5OH/O2/Ar at a pressure of 30 torr (4 kPa) with equivalence ratios ϕ = 1 and 2. It was shown that the replacement of part of ethylene with ethanol in the starting mixture lowered the concentration of a number of intermediate flame species, including soot precursors C3H3 and C6H6. These data are important for the development, analysis, and further improvement of detailed kinetic mechanisms for combustion of mixtures of hydrocarbon and oxygenated fuels.
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