Abstract
The effects of acylation on the enantiomeric separation of isopropyl esters of alanine, valine, allo-isoleucine, isoleucine, leucine and aspartic acid were investigated with a cross-linked polycyanoethyl vinyl siloxane- l-Val- tert-butylamide fused-silica capillary column. The gas chromatographic behaviour of N-formyl, N-acetyl, N-trifluoroacetyl and N-benzoyl derivatives of the amino acid isopropyl esters were studied. The chiral recognition mechanism of the solutes on diamide chiral stationary phases is discussed.
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