Investigation of the degradation behaviour of Methamidophos under microwave irradiation

Abstract

The microwave (MW) irradiation process has been developed to treat wastewater of methamidophos production. The different oxidants are used as catalyst. A variety of factors affecting MW degradation in the presence of oxidants were studied. The best degradation ratio of methamidophos can be obtained at the MW power of 750 W, with 0.05% amount of K 2S 2O 8, irradiation time of 6 min and 1.0 × 10 −4 mol/L methamidophos as initial concentration. The pH value almost has no effect on degradation methamidophos. The degradation ratio of methamidophos surpassed 96% within 6 min MW irradiation in the presence of K 2S 2O 8 in these optimal experimental conditions. The research on kinetics suggests that the process of treatment accords to the pseudo-first-order reaction. Simultaneously, UV/nano-TiO 2 and UV/nano-TiO 2/K 2S 2O 8 photocatalytic oxidation degradations of methamidophos were investigated. The experimental results indicated that the method of MW degradation of organic pollutants in the presence of oxidant was an advisable choice for treating organic wastewaters for nonor low-transparent and fuscous dye wastewaters.