Abstract

Proton and carbon-13 chemical shifts of para-substituted stilbenes have been measured. 1H-1H, 1H-13C COSY spectra were obtained to analyze unambiguously the chemical shifts of protons and carbons. A long range coupling between 2-H and α-H was observed in a 1H-1H COSY spectrum. The observed chemical shifts have been correlated with Hammett substituent parameters. Among ethenyl protons and carbons, all but the chemical shifts of α-H show good correlation with both dual substituent parameters and single substituent parameters. In addition to this finding, the excellent linear correlations of C-l, and 4′-H of 4-substituted trans-stilbenes are also reported. Besides the correlations of chemical shifts with Hammett parameters, a good correlation between the chemical shifts and the calculated charges of position C-4′ are reported.

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