Abstract

Polycrystalline Sm3(Fe1−xAlx)5O12 (x =0, 0.1, 0.2, 0.3, 0.4) samples were prepared in single phase form. Rietveld analysis of X-ray diffraction patterns shows that samples crystallize in cubic structure (space group: $$Ia\overline{3} d$$ ) with a systematic decrease in lattice constant with Al doping. Magnetization measurements show that all these samples exhibit ferrimagnetic transition whose transition temperature (Tc) decreases from 562 K for x =0 to 350 K for x =0.4 due to the dilution of Fe3+–O–Fe3+ networks. In addition to that they undergo spin reorientation transition at TSR~ 70 K with considerable magnetic irreversibility below TSR. Interestingly the x =0.4 sample undergoes magnetic compensation at 26 K. Improvement of frequency response of dielectric constant ( $$\varepsilon^{\prime}$$ ) and loss tangent (tan $$\delta$$ ) is observed upon Al doping in a wide frequency range of 102–109 Hz.

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