Investigation of structural, dielectric and magnetic properties of Ho substituted nanostructured lithium ferrites synthesized via auto-citric combustion route

Abstract

Abstract A comprehensive study on structural, spectral, magnetic and dielectric properties of holmium substituted (Ho3+) lithium ferrites; Li1.2Co0.4HoxFe2−xO4 (x = 0.00–0.15) synthesized via auto-citric combustion route has been carried out. The annealing temperature essential for complete decomposition of precipitates and spinel phase formation was found around 950 °C which was estimated from thermo-gravimetric analysis (TGA). The development of face centered cubic (FCC) spinel structure was confirmed from X-ray diffraction (XRD) analysis. However, the traces of an ortho phase (HoFeO3) were appeared for x ≥ 0.06 indicating the solubility limit of Ho3+ ions. The lattice constant ′a′ increased from 8.351 to 8.360 A upon Ho addition up to x = 0.06 and it decreased thereafter from 8.360 to 8.352 A. This decrease in lattice constant was attributed to the secondary phase formation revealing segregation of Ho3+ ions at grain boundaries. The porosity was found to decrease from 44 to 23% by the inclusion of Ho3+ ions. Fourier transform infrared spectra (FTIR) exhibited tetrahedral (v1) and octahedral (v2) intrinsic vibrational bands at 627 cm−1 and 479 cm−1 respectively and these bands revealed a shift with increasing Ho concentration. The variations in force constants (Ko and Kt) were calculated and discussed with the tetrahedral (rA) and octahedral (rB) bond length trends. The dielectric parameters have been investigated as a function of composition and frequency. The systematic addition of Ho gradually increased the ac conductivity from 8.97 × 103 to 5.56 × 104 (Ω-cm)−1 up to x = 0.12 and it subsequently decreased for x = 0.15. The complex impedance examination (Cole-Cole plots) confirmed a grain-interior phenomenon, effectively contributing to the dielectric properties. The coercivity was enhanced while the saturation magnetization (Ms) was lessened by the incorporation of Ho3+ ions. The maximum value of coercivity (706 Oe) was obtained for Li1.2Co0.4Ho0.12Fe1.88O4. The improved coercivity may suggest their utilization in perpendicular recording media applications.