Abstract

Interests in using nanofluids for enhanced oil recovery (EOR) applications has been increasing. Herein, a novel surfactant-free water-based nanofluid for EOR was constructed using active silica nanoparticles. Active silica nanoparticles were synthesized via condensation of hexanedioic acid with the −OH group of silica. Water-based nanofluid was obtained by transforming carboxyl into carboxylate on the surface of active silica nanoparticles in water. The particle size of the active silica nanoparticles in water ranged from 10 to 20 nm. The interfacial activity of the nanoparticles was endowed through the shape change of the active silica nanoparticle surface groups to minimize their interface energy. The morphology and surface components of the active silica nanoparticles were characterized by transmission electron microscopy and Fourier transform infrared spectroscopy. The interfacial activity of the active silica nanoparticles was proved through interfacial tension and interfacial dilational modulus meas...

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