Abstract
AbstractCage‐based small‐pore zeolites are promising catalysts for catalytic applications such as methanol‐to‐olefins to produce light olefins and selective catalytic reduction to mitigate NOx emissions. The present paper reports our recent studies on vapor‐phase adsorption of n‐hexane in a series of small‐pore zeolites with cages such as 3A, 4A, 5A, ITQ‐29, SSZ‐13, SSZ‐16, SSZ‐17, SSZ‐36, SSZ‐50, ITQ‐12, ZK‐5, and Rho. The effects of zeolite compositions and crystal sizes on the adsorption kinetics and capacity are investigated, demonstrating that n‐hexane adsorption is a useful tool for characterizing the effective pore sizes and volumes of small pore zeolites.
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