Abstract
Short-range atomic order in the MoO3-TeO2 glassy system has been studied by the neutron diffraction method. With increase of the amount of MoO3 from 20 to 50 mol %, a sequential transition 4 → (3 + 1) → 3 of the coordination state of tellurium with respect to oxygen was observed. Throughout this process, a formation of MoO5 and MoO4 groups was detected. The interpretation of the experimental radial distribution functions was performed by comparison with quasi-crystalline model curves (structure diffusion model).
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