Abstract

The reduction in the etch rate of isolated holes in SiOCH was investigated as functions of deposition condition of SiOCH, cap-layer presence, air-exposure time between lithography and etching, and degassing time between cap-layer etching and SiOCH etching. The amount of H 2O in the films was evaluated using thermal-desorption spectroscopy (TDS). We conclude that the H 2O adsorbed in SiOCH reduces the etch rate, and its degassing results in recovery of etch-rate reduction. Using the SiOCH film that can avoid the damage due to cap-layer deposition, the reduction in etch rate was restricted during two months of air exposure.

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