Abstract

Platinum electrocatalysts supported on multi- walled carbon nanotubes (MWCNTs) with various diame- ters and lengths were studied by using transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV) and Chronoampe- rometry. The results indicated that the MWCNTs with smaller diameter generated more amorphous carbon after a sonochemical oxidation treatment. Compared with the long MWCNTs, the short MWCNTs had more open ends, resulting in high-Pt dispersion and electrocatalytic activity towards methanol oxidation. Pt nanoparticles supported on short MWCNTs with a diameter of 30-50 nm exhibited the best Pt dispersion and highest methanol oxidation activity among the catalysts studied. The high activities of the cat- alysts based on short MWCNTs were due to both the intrinsic high activity of the ends of MWCNTs and a good Pt distribution.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.