Abstract

The reactions of representative organochlorosilanes and organochlorogermanes with alkali metal fluorides (LiF, NaF, KF, RbF, CsF) were investigated by NMR spectroscopy and showed not only the fluorination to organofluorosilanes or organofluorogermanes but also the formation of organofluorosilicates and organofluorogermanates. The synthesis and crystal structures of two new polymeric organofluorogermanates, [K][Ph2GeF3]∙0.75 MeCN and [Cs][Ph2GeF3]∙THF, are presented.

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