Investigation of photon-induced effects on some diode parameters and negative capacitance of the Schottky structure with Zn-doped organic polymer (PVA) interface

Abstract

Variation in the electrical parameters depending on illumination and the formation of negative capacitance (NC), and inductive behavior (IB) of Schottky structures interlaid with Zn:PVA, were executed by current/impedance-voltage (I/Z-V) measurements in the dark and under 200 mW cm−2 illuminance. To designate the voltage or calculation method effects on the ideality factor (n), barrier height (BH-Φ B ), and series resistance (R s ), these parameters were extracted from different methods. These parameters extracted through the Thermionic-emission (TE) theory, Ohm’s law, Norde and Cheung functions were compared with each other. The reverse bias ln(I R )−V R 0.5 plots were also drawn to designate the validity of Poole-Frenkel and Schottky emissions. In Z-V measurements, NC and related IB phenomena were observed at 500 kHz-fixed frequency in the dark and under illuminance. The interface states (D it ) variation depending on energy and voltage was obtained using I-V and C/G-V measurements and related equations. The calculations of the diffusion-potential (V D ), acceptor-atoms (N A ), Fermi-energy (E F ), and Φ B (C-V) values were performed by fitting the observed linear in the reverse bias C −2 -V plot. A detailed analysis of NC was performed via the drawn C/(G/ω)-I plots for positive voltages. All experimental results show that the used calculation method, illumination, and voltage are highly effective on the electrical parameters.