Abstract

The mathematical relationship between the orientational order parameters and the coherent neutron scattering cross section for a nematic liquid crystal is given. For deuterated para-azoxyanisole the single-molecule part of the cross section is evaluated within the meanfield approximation and combined with experimental results to give information about molecular orientational order in terms of 〈P2〉, 〈P4〉 and 〈P6〉. Both 〈P2〉 and 〈P4〉 are found necessary for describing the molecular order. Discrepancies between experimental and theoretical results are interpreted as possibly reflecting the inadequacy of the meanfield theory of Maier and Saupe.

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