Investigation of Liquid-Liquid Reaction Phenomena of Aluminum in Calcium Silicate Slag.

Abstract

To achieve better process control of silicon (Si) alloy production using aluminum as a reductant of calcium silicate (CaO-SiO2) slag, it is necessary to understand the reaction phenomena concerning the behavior of formed phases at the metal-slag interface during conversion. The interfacial interaction behavior of non-agitated melt was investigated using the sessile drop method for varying time and temperature, followed by EPMA phase analysis at the vicinity of the metal-slag interface. The most remarkable features of the reaction were the accumulation of solid calcium aluminate product layers at the Al alloy-slag interface and spontaneous emulsion of Si-alloy droplets in the slag phase. The reduction is strictly limited at 1550 °C due to the slow transfer of calcium aluminates away from the metal-slag interface into the partially liquid bulk slag. Reduction was significantly improved at 1600-1650 °C despite an interfacial layer being present, where the conversion rate is most intense in the first minutes of the liquid-liquid contact. A high mass transfer rate across the interface was shown related to the apparent interfacial tension depression of the wetting droplet along with a significant perturbed interface and emulsion due to Kelvin-Helmholtz instability driven by built-up interfacial charge at the interface. The increased reaction rate observed from 1550 °C to 1600-1650 °C for the non-agitated melt was attributed to the advantageous physical properties of the slag phase, which can be further regulated by the stoichiometry of metal-slag interactions and the composition of the slag.