Abstract

Positron-lifetime measurements have been made for poly (ether urethane) undoped and doped with [LiClO4]/[Unit]=0.05 in the temperature range of 120–340 K. The measured lifetime spectra were resolved into three components. The lifetime and the intensity of orthopositronium were used to evaluate the amount of the free volume in poly (ether urethane). It was found that the variation of ionic conductivity with temperature and salt concentration can be rationalised in terms of free volume consideration.

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