Investigation of interaction mechanisms during co-combustion of sewage sludge and coal slime: Combustion characteristics and NO/SO2 emission behavior

Abstract

Co-combustion of sewage sludge (SS) and coal slime (CS) is a promising method to achieve resource utilization of both solid wastes. However, the emission characteristics of NO/SO2 and the interaction mechanisms between SS and CS are unclear. In this paper, the co-combustion characteristics and NO/SO2 emission behavior of SS and CS were investigated using a thermogravimetric analyzer and a tube furnace combustion system, and the interactions between SS and CS were explored. The results revealed the presence of remarkable interactions between SS and CS during the co-combustion. For the combustion characteristics, non-catalytic factors (interaction between volatiles and heat synergy) and catalytic factors (catalysis of inorganic components) controlled the combustion stage of the heavy volatiles and fixed carbon of the blends, respectively, leading to an earlier combustion process. For NO and SO2 emission characteristics, SS-CS co-combustion had significant NO in-situ reduction and self-desulphurization characteristics at 800 °C and 900 °C. The best inhibition occurred at 900 °C and 50 % CS ratio, and NO and SO2 emission amounts were reduced by 0.25 mg/g and 1.37 mg/g, respectively, compared to the theoretical values. At 1000 °C, co-combustion promoted the emissions of both NO and SO2. The interaction mechanisms suggested that the reducing atmosphere created and the reducing gases released by SS combustion promoted the reduction of CS-NO, while the char formed by CS exhibited a significant reduction of SS-NO. In addition, the effect of CS addition on the mass transfer process enhanced the sulfur fixation of inorganic components in SS, which led to the suppression of SO2 production. These findings provide a better understanding of the interactions between SS and CS during SS-CS co-combustion.