Abstract

In order to explore hydrothermal carbonization (HTC) behavior of municipal solid wastes (MSW), four typical components, waste textile, wood, paper and food, were employed to perform HTC and co-HTC process. The experiments were conducted at 240 ○C and 90 min with a 1:12 solid/liquid ratio, where blending ratios of 1:3, 1:1 and 3:1 with waste textile were investigated. As expected, the increase of fixed carbon and carbon content improved the fuel potential of hydrochar. The synergistic index (SI) analysis clearly indicated that significant synergistic effects occurred during co-HTC process. Specifically, all the SI values of hydrochar yield from co-HTC of waste textile with wood and paper were negative, while all SI values of hydrochar yield for waste textile with food were positive. Particularly, the SI values of fuel ratio for all hydrochars were positive which suggested co-HTC could promote to enhance the coalification degree of hydrochars. However, the undesirable increment of O content for hydrochars (derived from 75%waste textile-25% waste food and 50%waste textile-50% waste food) decreased the high heating value. The combustion behavior and nth-order kinetic model analysis showed that hydrochars derived from co-HTC rendered a more stable and lasting combustion profile.

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