Investigation of H2S Solubility in Aqueous N- Methyldiethanolamine + Amine Functionalized UiO-66 as a nano solvent

Abstract

In this paper, the experimental solubility of hydrogen sulfide in aqueous N- Methyldiethanolamine + Amine Functionalized UiO-66 (UiO-66-NH2) was studied. UiO-66-NH2 was produced using solvothermal process, and its physicochemical properties were investigated by different techniques including XRD, TGA, TEM, BET, and FTIR to realize its crystalline structure, morphology, thermal stability, and porous structure. The Zeta potential of the solution was turned out to be about 26.6 mV (millivolt), meaning that UiO-66-NH2 particles are moderately stable in aqueous 40 wt.% MDEA. The solubility of hydrogen sulfide has been carried out using the isochoric saturation / or static method in two concentration grades of 0.1 and 0.5 wt.% of UiO-66-NH2 in the aqueous solution of 40 wt.% MDEA known as nanofluid. Experimental measurements were carried out at temperatures of 303.15 through 333.15 K, and pressures up 1100 kPa. Results showed that the addition of UiO-66-NH2 nanoparticles to the MDEA solution altered the results less than 3% , while the mean value of uncertainty reported in this work is about 4% , meaning that the addition of nanoparticles do not have remarkable effect on H2S solubility. In contrast, it causes an increased capacity of CO2 absorption of that solution up to 10%.