Abstract

Multivariate data analysis methods were applied to study the geographical and temporal distribution of tropospheric ozone in Catalonia (North-East Spain). Ozone data were collected during the period 2000–2004 in 41 sampling stations. Data analysis by multivariate curve resolution alternating least squares (MCR-ALS) allowed the recognition of three sub-regions within Catalonia according to their ozone variation patterns. Representation of loadings by means of geographical information systems (GIS) allowed a better visualisation of these areas. Daily, weekly and annual ozone profiles were determined for each sub-region. Principal component analysis (PCA) was applied within each sub-region to unravel the relationship between ozone variation and some other parameters, such as atmospheric pollutants (SO 2, H 2S, NO, NO 2, CO and particulate matter), as well as meteorological variables (temperature, relative humidity, solar radiation, pressure, precipitation and wind speed).

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