Investigation of free fatty acid reduction from mixed crude palm oil using 3D-printed rotor–stator hydrodynamic cavitation: An experimental study of geometric characteristics of the inner hole

Abstract

A continuous esterification process is employed to decrease the free fatty acid (FFA) concentration of FFA-rich mixed crude palm oil. Both optimal and recommended conditions are determined for the esterification reaction conditions and the geometry of the 3D-printed rotor design in the rotor–stator hydrodynamic cavitation reactor. This study is primarily concerned with the effect of the cavitation device configuration, especially the rotor design, on FFA reduction. Instead of conventional spherical or cylindrical drilled holes, a point angle cone-shaped hole is used to create cavities over the rotor surface. These point angles are adjusted to clarify their effect on FFA reduction. The response surface methodology is applied to determine the optimal concentrations of methanol and sulfuric acid, rotor speed, hole diameter and depth, and cone point angle. The recommended conditions are 20.8 wt% methanol, 2.6 wt% sulfuric acid, 3000 rpm, 5 mm hole diameter, 5 mm hole depth, and 110°, respectively. Under this configuration, the FFA content is reduced from 12.014 wt% to around 1 wt%. A maximum yield of 97.34 vol% esterified oil is obtained through a completed phase separation step, and 93.31 vol% pure oil is collected after the cleansing step. The recommended conditions result in reduced chemical usage, cheaper FFA reduction, and lower environmental impact. This creative rotor design effectively improves our understanding of the geometry of the cavitation device, thus enhancing the cavitation effect in industrial operations.