Abstract

It has been found that the length of the alkylene bridge in anion radicals of alkylenediphosphine dioxides influences the EPR spectra — an effect that is related to differences in structure of the ion pair. Temperature-dependent changes in the EPR spectra of anion radicals of diaryl (carbamoylmethyl)phosphine oxides are related to retarded rotation of the fragments of the anion radicals around the C-C bridge bond.

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