Abstract
This work concerned the electrorefining of UZr and UPuZr alloys on a solid aluminium cathode, in the LiCl–KCl eutectic melt containing U3+, Pu3+, Np3+, Zr2+ or Zr4+, Am3+, Nd3+, Y3+, Ce3+ and Gd3+ chlorides. During constant current electrolyses, the use of a cathodic cut-off potential (−1.25V versus Ag/AgCl) allowed to selectively deposit actinides (mainly U), while lanthanides remained in the salt. The aim was to determine the maximal load achievable on a single aluminium electrode. The total exchange charge was 4300C, which represents the deposition of 3.72g of actinides in 4.17g Al, yielding a composition of 44.6wt% An in Al. It was shown that the melting of the cathode contributed to increase the total amount of actinides deposited on the aluminium.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.