Abstract
Abstract Polydimethylsiloxane (PDMS) is widely used from biomedical to industrial applications due to its nontoxic, hydrophobic, and transparent characteristics. PDMS has good thermal and adhesion properties; however, its mechanical properties are comparatively weak. Therefore, PDMS is blended with various polymers to effectively improve its mechanical properties. In this study, polyurethane (PU)–polydimethylsiloxane (PDMS) blended coatings of different concentrations were applied on the AISI 316L stainless steel surface. Their effects on corrosion and tribocorrosion properties were investigated in Ringer’s solutions. The blended polymer coatings were characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The thermal properties of samples were examined by TGA and DSC. The surface images and cross-sectional were investigated using scanning electron microscopy (SEM). Tribocorrosion tests were carried out at open circuit potential (OCP). It was determined that hydrophobicity and thermal stability of polymer coating increased, while corrosion resistance slightly decreased with the increasing PDMS concentration in the polymer blended. The friction coefficient of blends decreased as the PU concentration increased. As a result, it was determined that the polymer-coated samples containing up to 50% PDMS prevented corrosive wear under the OCP wear test in Ringer’s solutions.
Highlights
Polydimethylsiloxane (PDMS) is widely used from biomedical to industrial applications due to its nontoxic, hydrophobic, and transparent characteristics
The results show that PU, PU75–PDMS25, and PU50–PDMS50 polymer coatings protected the surface of the substrate material
The hydrophobicity and the thermal stability of coatings increased, whereas corrosion resistance of coating slightly decreased with the increased PDMS concentration in the blend
Summary
Abstract: Polydimethylsiloxane (PDMS) is widely used from biomedical to industrial applications due to its nontoxic, hydrophobic, and transparent characteristics. PDMS has good thermal and adhesion properties; its mechanical properties are comparatively weak. PDMS is blended with various polymers to effectively improve its mechanical properties. Polyurethane (PU)–polydimethylsiloxane (PDMS) blended coatings of different concentrations were applied on the AISI 316L stainless steel surface. Their effects on corrosion and tribocorrosion properties were investigated in Ringer’s solutions. It was determined that hydrophobicity and thermal stability of polymer coating increased, while corrosion resistance slightly decreased with the increasing PDMS concentration in the polymer blended. It was determined that the polymer-coated samples containing up to 50% PDMS prevented corrosive wear under the OCP wear test in Ringer’s solutions
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