Abstract
A new mixed-ligand complex, Cd(S2CN(C4H9)2 2)2(2,2′-Bipy), was synthesized. A polycrystal X-ray diffraction analysis was performed (DRON-3M and DRON-UM1 diffractometers, CuKα radiation, Ni filter) and the crystal structure was determined [Enraf-Nonius CAD-4 automatic diffractometer, MoKα radiation, 2440 nonzero independent reflections, 153 refined structural parameters, R is 0.11 for I>2σ(I)]. Crystal data for C28H44CdN4S4 : a = 28.716(4), b = 6.848(6), c = 17.188(2) A, space group Pcca, V-3380.2(7) A3, Z = 4, M = 679.42, dcaU.= 1.335 g/cm3. The structure consists of monomeric molecules in which the cadmium atom has a distorted octahedral environment. The polycrystal diffraction analysis revealed that the complex is isostructural with the defined complex Zn(S2CN(C4Hg)2)2(2,2′-Bipy). A crystal-chemical search on metal dialkyldithiocarbamates in the Cambridge Structural Database was accomplished and isostructural pairs of Zn and Cd metal complexes were found.
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