Abstract

Thermodynamic stability constants of the complexes of various dipositively charged metal ions, UO 2(II), Cu(II), Zn(II), Cd(II), Ni(II), Co(II) and Mn(II), with 2,4-pentanedione-1-(3-chlorophenylhydrazone) have been determined potentiometrically, in 50% (v/v) dioxan-water medium, at different temperatures and ionic strengths. The stability constants and S min values have been calculated at different ionic strengths and temperatures. The method of Bjerrum and Calvin, as modified by Irving and Rossotti, has been used to find out the values of n̄ and pL. The thermodynamic parameters Δ G, Δ H and Δ S have also been evaluated from temperature-dependent data

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