Abstract

Substitution of chloride ions in AuCl 4 − with ethylenediamine (en) and propylenediamine (tn) is studied by capillary zone electrophoresis at I = 0.05 M and T = 25°C. The substitution constants are determined: AuenCl 2 + + en = Auen 2 3+ + 2Cl–, logK2 = 10.4; AuCl 4 − + tn = AutnCl 2 + + 2Cl–, logK1 = 16.1; AutnCl 2 + + tn = Autn3+2 + 2Cl–, logK2 = 12.0.

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