Investigation of chemoconvection in vibration fields.

Abstract

This study is devoted to the investigation of the chemoconvection in a two-layer miscible system caused by the neutralisation reaction proceeding in the convective-controlled (CC) regime under the influence of vertical vibrations. The CC regime without vibrational influence is characterized by the development of a density wave and vigorous convection in the upper layer, ensuring a high reaction rate and forcing the reaction front to move downwards more rapidly than in the well-known diffusive-controlled (DC) regime. It is shown that vibrations lead to some deceleration of the convection that depends both on the magnitude of the vibrational acceleration and on the initial concentrations of the reagents. Analysis of the system behaviour depending on the dimensionless parameters is carried out. It is demonstrated that the theory of thermal vibrational convection may be applied for reacting systems on quasi-steady time intervals.