Investigation of changes in the iodine concentrations of oceanic sediment and terrestrial soil samples after thermal drying.

Abstract

To certify the suitability of pretreatment by thermal drying to measure iodine concentrations of oceanic sediment and terrestrial soil samples, changes in iodine concentrations after drying (50, 80 or 85, and 110°C for 48h) were examined using the samples in addition to a terrestrial plant (pine needles), which was selected as an intact organic sample. The iodine concentrations per wet weight of the sediment and soil samples processed by thermal drying were comparable to those of the raw samples at all temperatures. However, the concentrations of the plant samples dried at 85 and 110°C were lower than those of the raw samples. The lower concentrations of the plant samples at higher temperatures were considered to be derived from the volatilization of a part of the plant's organic matter. Finally, these results suggested that the iodine concentrations in oceanic sediment and terrestrial soil samples scarcely change after thermal drying at 110°C, although the concentrations may decrease when these samples include high contributions of fresh organic matter.