Abstract

The intercalation chemistry of Mn 2P 2S 6 is investigated with respect to characteristics important for chemical sensors. Questions such as kinetics, sensitivity, and reversibility are addressed. Ammonia gas is chosen as the analyte for simplicity. Both large single crystals and pressed powdered pellets of Mn 2P 2S 6 are used. The rapid change in the physical properties of the Mn 2P 2S 6 host lattice upon intercalation with ammonia suggests that this type of insertion chemistry is a fruitful area for further study with respect to chemical sensor science.

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