Abstract
Ammonia has received significant attention as a carbon-free fuel and a promising carrier of hydrogen. Ammonia cracking presents an effective method for on-line hydrogen production, eliminating the need for hydrogen transportation and storage. This paper aims to study the comprehensive impacts of ammonia cracking ratio (CR) and equivalence ratio (ER) on combustion performance and NO/N2O/NO2 behaviors under lean-burn operation mode. The ammonia/hydrogen mechanism was updated and simplified to enhance the calculation efficiency in 3D simulation. Visualization measurements for flame propagation and NO and 3D simulations were simultaneously performed in a constant volume combustion chamber (CVCC). The results showed that ammonia blending with the cracked gas of H2/N2 for CR can significantly enhance the combustion rate under lean-burn operation at an ER of 0.5. Nevertheless, this enhancement leads to an increase in NOx due to elevated OH and HNO formation, regardless of N2 separation. In the context of varying ER, ranging from 0.5 to 0.3, the study revealed that increasing CR combined by decreasing ER at a certain point can sustain a higher combustion rate while reducing NOx emissions. For instance, CR45ER0.4 yields a much shorter combustion duration and lower NOx compared to pure ammonia at an ER of 1.0. However, a further increase in CR, such as CR80ER0.3, results in higher NOx emissions again. Moreover, complete cracking or separation from the non-cracked ammonia proves favorable for NOx elimination due to the absence of fuel-NO. The current study provides insights on high-efficiency and clean zero-carbon combustion technology.
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