Abstract
Glass-ceramic coatings on nickel and its alloys are produced from organic-inorganic hybrids by the sol-gel method. The coatings are applied using sol-gel systems composed of tetraethoxysilane (inorganic dopant), as well as of finely dispersed oxide and ultradispersed hybrid fillers. Acrylic and methacrylic acid derivatives are taken as organic modifiers. Oligocarbonate dimethacrylate-substituted tetranuclear titanium oxide clusters are used as the ultradispersed hybrid filler. The influence of the organic modifiers and ultradispersed hybrid fillers on the physicochemical processes occurring in the sol-gel systems and on the electrical parameters of the coatings are experimentally studied, and the data obtained are analyzed.
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