Investigation into the electrochemical advanced oxidation of p-arsanilic acid: Peculiar role of electrolytes and unexpected formation of coupling byproducts

Abstract

Although banned in some countries, p-arsanilic acid (ASA) is still widely used as feed additive in poultry production. As a result, ASA is usually released into the aquatic environment without any treatments. Although ASA exhibits low toxicity, it can be transformed into highly toxic aromatic amines and inorganic arsenic species (As (V) as H2AsO4− and HAsO42−) under natural environmental conditions. Hence, it is necessary to develop efficient technologies for its removal or degradation. In this contribution, electrochemical advanced oxidation technology with boron-doped diamond (BDD) had been initially used to degrade ASA pollutants. A five-level central composite rotatable design (CCRD) was implemented to optimize the various influencing factors involved, among applied current density, NaCl concentration, Na2SO4 concentration and NaHCO3 concentration on the oxidation efficiency; the latter was assessed in terms of ASA degradation percentage. The results obtained highlighted the unique and important roles of electrolytes during the electrolytic oxidations. Meanwhile, the major degradation byproducts detected were also strongly dependent on the electrolyte adopted. In particular, several oligomer byproducts with novel structures were initially identified in BDD-treated ASA solutions. Two different electrochemical transformation pathways of ASA on BDD anode were thus proposed. This study demonstrated the effectiveness of BDD technology in the degradation of ASA, as well as the potential minor risk of its application in actual ASA wastewater treatment.