Abstract

Furan reacts with acrylnitrile and the reaction proceeds as diene synthesis with formation of stereoisomeric nitriles of 3,6-endoxotetrаhydrоbenzoic acid. The configurations were еestablished by PMR-spectra. 2-Methylfurаn reacts in a similar way. Some aspects of correlation of diene synthesis and substitutive addition in the furan series are discussed. Authors: Yu. K. Yur'ev, N. S. Zefirov, R. A. Ivanova, G. Yu. Pek English Translation in Chemistry of Heterocyclic Compounds , 1965, 1 (1), pp 1-4 http://link.springer.com/article/10.1007/BF01168907

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