Investigating the compatibility of nickel coated carbon nanotubes and cementitious composites through experimental evidence and theoretical calculations

Abstract

Nickel coated multi-walled carbon nanotubes (NiMCNTs) are favorable reinforcing nanofillers for modifying cementitious composites due to their preeminent mechanical properties, electrical conductivity, thermal properties and dispersibility. This paper investigates the mechanical properties and compatibility of NiMCNTs filled cementitious composites, having two different types of cement, two water to cement ratios, and two dosages of five types of NiMCNTs. The results show that 0.06 vol% NiMCNTs with small aspect ratios can significantly enhance the mechanical properties of cementitious composites, while NiMCNTs with large aspect ratios play a better strengthening effect at 0.03 vol%. The flexural strength/toughness of cementitious composites containing 0.06 vol% NiMCNTs with an aspect ratio of 200 can be increased by 19.65%/116.78%. Adding 0.03 vol% NiMCNTs with an aspect ratio of 1000 enhances the compressive strength/toughness of composites by 18.61%/47.44%. Besides, NiMCNTs have preferable compatibility to cementitious composites prepared by P·O 42.5R cement with a water to cement ratio of 0.3. The enhancement mechanism is related to the denser microstructure and effective suppression of microcracks in the cementitious matrix by NiMCNTs with filling, bridging and pull-out effects, as well as the high interface bond strength between NiMCNTs and matrix. A strength prediction model for NiMCNTs reinforced cementitious composites is also established to estimate the mechanical strength of cementitious composites containing NiMCNTs with different aspect ratios/contents, showing a small relative error within ±6%/±13% for predicted flexural/compressive strength values in comparison with the experimental results.