Investigating how oxygen levels and particle size impact the thermodynamics of low temperature coal oxidation: A case study using weakly caking coal

Abstract

Oxygen concentration and particle size play critical roles in the combustion of coal. Notably, the low temperature oxidation stage is considered pivotal for coal spontaneous combustion (CSC). In this study, we examined the exothermic oxidation of low-temperature weakly caking coal. We used a C80 microcalorimeter to assess the impact of different oxygen concentrations and particle sizes. For weakly caking coal during low-temperature oxidation, the heat flow (HF) curve decreases as oxygen concentration drops. The characteristic temperature increases, and the HF curve shows a noticeable lag. Under identical external conditions, decreasing the particle size of coal results in a reduced minimum floating coal thickness, lowers the oxygen concentration needed for CSC, increases the upper-limit of air leakage intensity, and makes the coal more susceptible to CSC. Reducing the particle size significantly increases the exothermic heat release during low-temperature oxidation, leading to a higher risk of CSC. These research results not only deepen the understanding of the law of coal spontaneous combustion, but also provide a scientific basis for improving the technical level of coal spontaneous combustion fire prevention and control.