Investigating BiMeVOx compounds as potential photoelectrochemical and electrochemical materials for renewable hydrogen production

Abstract

In this study, BiMeVOx compounds (where Me: Co, Mo, Ce, Zr) were synthesized and characterized as potential photoelectrochemical materials for solar water splitting, the hydrogen evolution reaction (HER), and oxygen evolution reaction (OER). The analysis confirmed the successful formation of phase BiMeVOx compounds with the desired crystal structure. Among the tested materials, BiCoVOx(800) showed the highest photocurrent density (674 μA cm−2) and HER/OER activity (Tafel slope: HER = 100 mV dec−1 and OER = 75 mV dec−1), followed by BiMoVOx(800), BiCeVOx(800), and BiZrVOx(800). The superior photoelectrochemical performance of BiCoVOx(800) can be attributed to its unique electronic structure and optimized band alignment, which promote efficient charge separation and facilitate the water splitting and hydrogen evolution processes. The findings of this study highlight the promising potential of the synthesized BiMeVOx materials, particularly BiCoVOx, as efficient photoelectrochemical catalysts for water splitting. These results contribute to the advancement of renewable energy technologies and provide valuable insights for the design and development of novel photoactive materials.